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Gold Catalyzed Hydroamination of Alkynes and Allenes


Technology Application

Hydroamination of alkynes and allenes Production of pharmaceuticals/bioactive molecules


Detailed Technology Description

None


Application No.

8580990


Others

Background

Nitrogen-carbon bonds are found in a variety of compounds, ranging from pharmaceuticals to chemical feedstocks. Specifically, the formation of C-N bonds is done via hydroamination, which adds the N-H bond of an amine group to a carbon-carbon bond via a catalyst, which is a compound that increases the rate of a chemical reaction without being consumed. This process is especially important in the synthesis of biologically active compounds.


Ammonia is among the cheapest, most readily available bulk chemicals, which has led to a widespread interest in developing techniques that can combine ammonia with organic molecules. Of particular interest is combining ammonia with multiple-bonded carbon atoms (such as those in alkynes and allenes).


Related Materials

Lavallo, V. et al. Homogeneous Catalytic Hydroamination of Alkynes and Allenes with Ammonia. Angewandte Chemie. 47, 28 (2008)


Tech ID/UC Case

29208/2008-598-0


Related Cases

2008-598-0


Country/Region

USA

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