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Solution Synthesis and Deposition of Kesterite Copper Zinc Tin Chalcogenide Films

Technology Benefits
Readily achievable uniform chemical composition distribution (active layer) Precise control of both structural and electrical properties of the solar cell active layer Reduced costs Environmental friendly
Technology Application
Production of all second generation and future solar cells
Detailed Technology Description
Researchers at UCLA have developed a solution based method for Cu2ZnSnS4 (CZTS) precursor synthesis. This method provides a powerful tool for depositing uniform films in chemical compositions for large scale device fabrication.
Supplementary Information
Inventor: YANG, Yang | YANG, Wenbing | LI, Shenghan | HSU, Wan-Ching
Priority Number: WO2012174551A3
IPC Current: H01L005148 | H01L005146
Assignee Applicant: The Regents of the University of California
Title: INORGANIC SOLUTION AND SOLUTION PROCESS FOR ELECTRONIC AND ELECTRO-OPTIC DEVICES | SOLUTION INORGANIQUE ET PROCÉDÉ D'OBTENTION DE SOLUTION POUR DISPOSITIFS ÉLECTRONIQUES ET ÉLECTRO-OPTIQUES
Usefulness: INORGANIC SOLUTION AND SOLUTION PROCESS FOR ELECTRONIC AND ELECTRO-OPTIC DEVICES | SOLUTION INORGANIQUE ET PROCÉDÉ D'OBTENTION DE SOLUTION POUR DISPOSITIFS ÉLECTRONIQUES ET ÉLECTRO-OPTIQUES
Summary: Solution is used for manufacturing Kesterite film on substructure of electronic or electro-optic device (all claimed), and photovoltaic device e.g. solar cell.
Novelty: Solution for forming for manufacturing Kesterite film for electronic or electro-optic device, contains solvent, additive chosen from amine-containing compounds and solute comprising aluminum, gallium, indium, germanium, tin or antimony
Industry
Environmental/Green Technology
Sub Category
Solar Cell
Application No.
9502600
Others

State Of Development

Devices have been fabricated with the structure of ITO-glass/CZTS/CdS/Ag and the method was tested and validated in the lab. Photovoltaic effect has been demonstrated from the initial solution processed CZTS device and current-voltage characterization shows an excellent rectifying effect of the p-n junction between CZTS/CdS with an ideality factor of 1.3.


Background

Developing a feasible method for renewable energy generation has become a focus due to concerns over global warming and increased demand for energy. Among renewable energy sources, solar energy has attracted the most attention but production scaling and rising costs are hurdles for photovoltaic technologies to compete with traditionally generated power.

In so called "second generation" solar cells, CIGS and its related materials are utilized for the fabrication of low-cost and high-efficiency solar cells. However, the continued supply of the rare metal indium in the mass production stage has created major concerns.


Additional Technologies by these Inventors


Tech ID/UC Case

22252/2011-410-0


Related Cases

2011-410-0

*Abstract
UCLA researchers in the Department of Material Science and Engineering have developed a solution based method for Cu2ZnSnS4 (CZTS) precursor synthesis that uses earth abundant and environmental friendly materials as a viable alternative to Cu(In,Ga)Se2 (CIGS) for use in solar cells.
*IP Issue Date
Nov 22, 2016
*Principal Investigator

Name: Wan-Ching Hsu

Department:


Name: Shenghan Li

Department:


Name: Wenbing Yang

Department:


Name: Yang Yang

Department:

Country/Region
USA

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