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BORGS: Beyond Open Reticulated Geometries

Technology Benefits

Combines adsorption, conduction, molecular recognition, and switchingEase to functionalize active sitesIncreased sensitivity

Technology Application

Gas separation or purificationSensorsMilitary or personal safety - nerve agent gas and explosion detection

Detailed Technology Description

Researchers at UCLA have improved MOF structures by creating Beyond Open Reticulated Geometry MOFs (BORG-MOFs) and a method of fabrication. The molecular recognition sites impart selectivity in binding and identifying an incoming agent, while the adjustment of pore metrics allows for size and shape selectivity. Major improvements over current MOF structures include the BORG-MOFs' ease of functionalization of active sites and their ability to combine adsorption, conduction, molecular recognition, and switching into one material. BORG-MOFs also have increased porosity over traditional MOFs, resulting in more receptor sites and increased sensitivity.

Supplementary Information

Patent Number: US20110137025A1
Application Number: US2010996378A
Inventor: Yaghi, Omar M | Li, Qiaowei | Miljanic, Ognjen S | Zhang, Wenya | Stoddart, James Frasere
Priority Date: 5 Jun 2008
Priority Number: US20110137025A1
Application Date: 18 Feb 2011
Publication Date: 9 Jun 2011
IPC Current: C07D032300 | C07C006528 | C07C022938 | C07D040104 | C07D040714 | C07D040904 | C07D048722 | C07D049304 | C07D049504 | C07D049718 | C07F000306
US Class: 540145 | 540465 | 540472 | 546002 | 546257 | 548402 | 548453 | 549003 | 549011 | 549039 | 549208 | 549349 | 549351 | 549364 | 556118 | 560039 | 562451 | 562473
Assignee Applicant: The Regents of the University of California
Title: CHEMICAL FRAMEWORK COMPOSITIONS AND METHODS OF USE
Usefulness: CHEMICAL FRAMEWORK COMPOSITIONS AND METHODS OF USE
Summary: As metal organic framework useful for microelectronic switch, sensor, gas separation device, small molecule separation/purification device, guest recognition device, and chiral molecule separation medium (claimed); for generating beyond open reticulated geometries (BORGs); as gas storage materials.
Novelty: Metal organic framework useful for e.g. microelectronic switch, sensor and gas separation device comprises moieties with stereospecific and stereoelectronic control, pseudorotaxanes, rotaxanes, catenanes, chelates or cryptand structures

Industry

Chemical/Material

Sub Category

Chemical/Material Application

Application No.

8946454

Others

State Of Development

 Initial synthesis and fabrication of MOF structure is achieved.

Background

Metal-organic frameworks are crystalline compounds consisting of metal ions or clusters coordinated to often rigid organic molecules to form one-, two-, or three-dimensional structures that can be porous. These structures, while robust, usually contain only passive sites for adsorption, lacking molecular recognition and switching capabilities.

Additional Technologies by these Inventors

• Carbon Dioxide Capture and Storage Using Open Frameworks
• Metallation of Open Frameworks
• Conductive Open Frameworks
• Multi-Dimensional Networks
• Adsorptive Gas Separation of Carbon Dioxide from Methane by Zeolitic Imidazolate Frameworks (ZIFs)
• Reversible Hydrogen Storage Using Metal-Organic Frameworks (MOFs)
• Reversible Ethylene Oxide Capture in Metal Organic Frameworks (MOFs)
• Catalytic Coupling Reactions Using Frameworks with Open-Metal-Sites
• Design and Synthesis of New Metal-Organic Frameworks (MOFs) With Unique Topologies
• Oxidative CH Activation of Non-Activated Alkanes Using Metal-Organic Frameworks (MOFs) as Catalysts

Tech ID/UC Case

21609/2008-378-0

Related Cases

2008-378-0

*Abstract

UCLA scientists have developed porous metal-organic frameworks (MOFs) capable of combining adsorption, conduction, molecular recognition, and switching into one material.

*Applications

• Gas separation or purification
• Sensors
• Military or personal safety - nerve agent gas and explosion detection

*IP Issue Date

Feb 3, 2015

*Principal Investigator

Name: Qiaowei Li

Department:

Name: Ognjen Miljanic

Department:

Name: James Stoddart

Department:

Name: Omar Yaghi

Department:

Name: Wenyu Zhang

Department:

Country/Region

USA