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一種進行不對稱催化氫化反應的方法

总结
The invention discloses a catalytic asymmetric hydrogenation reaction. Of the present invention is the role of chiral catalyst, H2 of the prochiral unsaturated compounds to addition reaction to obtain the chiral product, wherein the solvent used in the reaction liquid polyethylene glycol compound. The method of the invention not only to the reaction system to achieve a homogeneous catalyst and product separation, recycling, and the polyethylene glycols used in the reaction medium is a safe, inexpensive, and environmentally friendly green solvents, reducing environmental pollution. Catalytic hydrogenation reaction with the existing methods, the conversion of the substrate and product enantioselectivity can achieve the same level of recovery in some experiments, the product which had been improved enantioselectivity; hand obtained of the product as an important pharmaceutical intermediates, has important application prospect.
附加资料
Inventor: FAN, Qing-hua | ZHOU, Hai-feng | HE, Yan-mei | TANG, Wei-jun | CHEN, Xin-zi | GU, Lian-quan
Priority Number: CN101117304B
IPC Current: C07B005300 | C07C003322 | C07C0053122 | C07C005730 | C07C005901 | C07C027122
Assignee Applicant: Chinese Academy of Science Institute of Chemistry |The Hong Kong University of Science and Technology
Title: Method for asymmetric catalytic hydrogenation
Usefulness: Method for asymmetric catalytic hydrogenation
Summary: Asymmetric catalytic hydrogenation of last unsaturated chiral compound and forming chiral product used as medical intermediate.
Novelty: Asymmetric catalytic hydrogenation for forming chiral product used as medical intermediate, involves carrying out addition reaction of last unsaturated chiral compound by hydrogen in presence of chiral catalyst and solvent
主要类别
化工/材料
细分类别
化工/材料应用
其他
CHAN S.C., Albert
国家/地区
中国内地

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