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Improved Alumina Catalyst

Detailed Technology Description

Introduction Alumina has been used as a catalyst in a wide variety of industrial processes for many years. Even modest improvements in alumina catalysts can have a significant impact on efficiencies of production of a very wide variety of chemical compounds. There is a continuing commercial need for new tailored alumina catalysts that can more efficiently produce existing chemical compounds, or that lend themselves to the production of new compounds. Description of Technology A mesostructured gamma-alumina is prepared by hydrolyzing an aluminum salt or alkoxide in the presence of a polyethylene oxide surfactant, the latter directing the formation of a mesostructure with pore walls comprised of the alumina. The final product results from a subsequent thermal dehydration process, resulting in a mesostructured alumina with high surface area and large interconnected pores of well-defined size. The result is high surface area (typically beyond 200-250 meters squared/g), and pore sizes typically well beyond 0.5 cc/g. Alumina catalysts tailored to production of a given chemical are determined from the beginning aluminum compound, surfactant, and other details of the preparation process for the alumina catalyst.  Key BenefitsLow cost: The compositions can be prepared from low-cost aluminum salts and non-toxic surfactants. Selectivity: The invention provides an improved ability to determine pore size and some characteristics of pore shape, including the ability to obtain improved uniformity in the selected pore size and connectivity between pores. The result is a significantly improved ability to control which chemical reactions will be catalyzed at the alumina surface, with accompanying reduction of unwanted byproducts due to the higher catalytic selectivity. Reactivity: The improved performance of the alumina catalysts means that catalytic production efficiencies could be higher than current levels by substantial factors for a wide variety of chemical compounds. The improved control on pore size and shape also enables reductions in unwanted byproducts. Use in existing plants: Since the invention provides improvements to existing technologies for producing alumina catalysts tailored to the production of specified chemical compounds, but with superior performance of the new alumina catalysts, the invention could typically be used in existing production facilities following changeout modifications. Applications This invention could be used for a wide variety of applications where alumina is already being used as a catalyst or catalyst substrate. Major examples include chemical production using petroleum as a feedstock, catalytic converters for cars, environmental cleanup equipment, adsorbants, and alumina catalysts for industrial applications. Patent Status US 7,090,824 B2 (issued 08/15/06) Inventors Thomas Pinnavaia, Zhaorong Zhang, Randall Hicks, Thomas Pauly Tech ID TEC2001-0036

*Abstract

None

*Principal Investigator

Name: Thomas Pinnavaia, Professor

Department: Department of Chemistry

Name: Zhaorong Zhang, Research Scientist

Department:

Name: Randall Hicks

Department:

Name: Thomas Pauly

Department: Non-MSU Employee

Country/Region

USA