Living Insertion/Cyclization/Ring-Opening Polymerization: A Strategy for the Synthesis of Functional Propylene Copolymers and Block Copolymers
- 详细技术说明
- Polymerization of 1,5-hexadiene with a perfluorinated bis(phenoxyimine) catalyst system is reported
- *Abstract
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Polymerization of 1,5-hexadiene with a perfluorinated bis(phenoxyimine) catalyst system is reported. The microstructure of the polymer contains the expected methylene-1,3-cyclopentane units as well as 3-vinyl tetramethylene units. A mechanism for formation of this polymer is proposed. This unusual reaction is also employed in the synthesis of monodispersed vinyl-functional polypropylene copolymers and block copolymers.
- *Licensing
- Jeff Fearn, Senior Technology Commercialization and Liaison Officerjcf55@cornell.edu607-254-4502
- 其他
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None
- 国家/地区
- 美国
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