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Oxidative CH Activation of Non-Activated Alkanes Using Metal-Organic Frameworks (MOFs) as Catalysts

技术优势

• Applicable for large scale chemical processes• MOF catalysts are easily produced and can be recycled• Catalysts have high chemical and temperature stability

技术应用

• Catalyzing chemical reactions to generate acetic acid and alcohols

详细技术说明

Dr. Omar Yaghi and colleagues at UCLA have developed two Vanadium-containing metal organic frameworks that can serve as a catalyst in the synthesis of acetic acid from methane. These catalysts give up to 70% yield and 100% selectivity. This is the first non-precious metal containing catalyst for such reactions.

*Abstract

UCLA researchers in the Department of Chemistry and Biochemistry have developed two novel organic framework-based catalysts used in CH activation during the process of converting methane into acetic acid. These catalysts demonstrate high efficiency and specificity, combined with the great chemical stability and reproducibility seen with organic framework materials.

*IP Issue Date

Aug 11, 2015

*Principal Investigation

Name: Anh Thi Phuong Phan

Department:

Name: Omar Yaghi

Department:

Name: Alexander Czaja

Department:

申请号码

9102609

其他

State Of Development

The Vanadium-containing MOF has been successfully generated and tested for oxidative CH-activation in the process of yielding acetic acid from methane.

Background

Methane is a great source of cost and environmental-friendly carbon-fuel. The conversion of methane into useful molecules, such as acetic acid, has been a long standing challenge due to the strong C-H bond of methane. Current catalysts being used for C-H activation in the conversion of methane directly to acetic acid include Rh or Ir compounds. Utilizing such catalysts require high capital and is energy intensive. Furthermore, such catalysts are low in efficiency and selectivity. Novel catalysts that can enhance the production of acetic acid from methane will greatly benefit the chemical processing industry.

Additional Technologies by these Inventors

• Carbon Dioxide Capture and Storage Using Open Frameworks
• Metallation of Open Frameworks
• BORGS: Beyond Open Reticulated Geometries
• Conductive Open Frameworks
• Multi-Dimensional Networks
• Adsorptive Gas Separation of Carbon Dioxide from Methane by Zeolitic Imidazolate Frameworks (ZIFs)
• Reversible Hydrogen Storage Using Metal-Organic Frameworks (MOFs)
• Reversible Ethylene Oxide Capture in Metal Organic Frameworks (MOFs)
• Catalytic Coupling Reactions Using Frameworks with Open-Metal-Sites
• Design and Synthesis of New Metal-Organic Frameworks (MOFs) With Unique Topologies

Tech ID/UC Case

25269/2010-969-0

Related Cases

2010-969-0

国家/地区

美国