Preparation of organometallic complexes useful as enantioselective oxidation reaction catalysts, by mixing metallocene chloride, chiral ligand and organic alkaline compound
- 详细技术说明
- None
- *Abstract
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A metallocene chloride is mixed with a chiral ligand compound and an organic alkaline compound in a solvent. A method for preparing chiral organometallic metallocene complexes comprises the following steps: (1) mixing a metallocene chloride with a chiral ligand compound such as a chiral metallocene diol and an organic alkaline compound in a solvent and in a given metallocene/chiral ligand molar ratio and given alkali/chiral ligand molar ratio under an inert atmosphere; and (2) separating the unconverted metallocene and organometallic complex salts.
- *Principal Investigation
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Name: Rafael Van Grieken, Researcher
Department: Chemical and Enviromental Dpt.
- 附加资料
- Patent Number: ES2259896B1
Application Number: ES20043011A
Inventor: VAN GRIEKEN SALVADOR RAFAEL | CALLEJA PARDO GUILLERMO | GARCIA MUNOZ RAFAEL ANGEL | IGLESIAS MORAN JOSE
Priority Date: 17 Dec 2004
Priority Number: ES2259896B1
Application Date: 17 Dec 2004
Publication Date: 1 Nov 2007
IPC Current: C07F001700 | C07D030119
Assignee Applicant: Univ Rey Juan Carlos
Title: PROCEDIMIENTO PARA LA SINTESIS DE COMPLEJOS ORGANOMETALICOS METALOCENICOS QUIRALES Y SU USO COMO CATALIZADORES DE OXIDACION ENANTIOSELECTIVA
Usefulness: PROCEDIMIENTO PARA LA SINTESIS DE COMPLEJOS ORGANOMETALICOS METALOCENICOS QUIRALES Y SU USO COMO CATALIZADORES DE OXIDACION ENANTIOSELECTIVA
Summary: The complexes are used as catalysts for enantioselective oxidation reactions, e.g. for olefin epoxidation reactions (claimed).
Novelty: Preparation of organometallic complexes useful as enantioselective oxidation reaction catalysts, by mixing metallocene chloride, chiral ligand and organic alkaline compound
- 主要类别
- 化工/材料
- 细分类别
- 化工/材料应用
- 国家/地区
- 美国
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